Miggidy:
There are plenty of "book collections" about the Vedas. They can be found in just about any bookstore. But these are predominantly speculations and conjectures about the Vedas rather than actual direct transliteration from the original Sanskrit texts.
It is similar to a person unfamiliar with Greek and Aramaic attempting to write in english a "collection" of Biblical scripture. It is not a pure transliteration (direct representation of characters from another alphabet), nor a concise translation (explanation or interpretation of a different language). Just as I doubt you would recommend a Bible collection authored by some unqualified opportunist, my opinion is that if one is to read the Vedas they should read them as they are, by a bona fide acarya, or spiritual master.
There are the 4 main Vedas (Rg, Yajur, Sama, Atharva), then there are the supplements to them, such as the Puranas, the Upanisads, the Vedanta-sutra, etc. Then there is the Mahabharata, within which is the Bhagavad-gita, the song of God, and which is the scientific textbook for beginning to understand the difference between spirit and matter. It is spoken by Sri Krsna to Arjuna on the battlefield of Kuruksetra, and is the preliminary text for one in this Kali-yuga. Originally there were only the 4 main Vedas, but as Kali-yuga (the age of quarrel and vice) approached, Vyasadeva foresaw the necessity to make these difficult teachings more accessible to the fallen souls. We are those fallen souls, and for us in this degraded condition Vyasadeva has given us the "5th" Veda, the Mahabharata, and Vyasadeva's own commentaries on the Vedas in the form of the Srimad-Bhagavatam (ripened fruit of the tree of knowledge), as a means of beginning to understand the intricate and heavy knowledge of the Vedas.
I would recommend the Bhagavad-gita by His Divine Grace A.C. Bhaktivedanta Swami Prabhupada. He is world-reknowned for his consummate Sanksrit knowledge, and in his gita he gives original Sanskrit, roman transliteration, english equivalents, and translations and purports. There is even Sanskrit pronunciation guide which explains how to read and say the original text. This book explains the heavy Vedic philosophy and deep spiritual subjects with crystal clarity and is very easy to read. If you are seriously interested in reading the Bhagavad-gita I will shoot you one for free.
Or if anybody else wants one they can just send me a pm or email and I will lace them up for free.
Bhagavad-gita Ch. 2 Text 20:
"For the soul there is never birth nor death. Nor, having once been, does he ever cease to be. He is unborn, eternal, ever-existing, undying and primeval. He is not slain when the body is slain."