u need to learn how to create graphics...so illustrator and photoshop...if you dont care much about grahics, you can go straight into dreamwear or golive and use CSS, xml., html ...with CSS and XML you can create some interesting layouts designs
Frontpage is weak, Dreamweaver is by far much better. I do agree with rubiqkz on learning html but look deep into dreamweavers help files....its got a lot of shit to teach.
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Learn html, http://www.htmlgoodies.com , read the articles on it. Its important to understand how tables and frames and everything work and correspond to eachother. Then as your learning, you can get more comfortable with dreamweaver over time, it doesn't happen over night. For 2d graphics, I reccomend Adobe Photoshop, or you can start a step down with Jasc Paint Shop Pro and move gradual to Adobe Photoshop. Take your time, be patient if your serious.